Alloy Steel

The inner world of metal

Definition of Alloy Steel

In addition to iron and carbon, alloy steel is called alloy steel by adding other alloying elements. An iron-carbon alloy formed by adding an appropriate amount of one or more alloying elements on the basis of ordinary carbon steel. According to the difference of added elements and appropriate processing technology, special properties such as high strength, high toughness, wear resistance, corrosion resistance, low temperature resistance, high temperature resistance, and non-magnetic properties can be obtained.

The most important and desirable changes to alloy steel are:

*Enhanced hardenability.

*Enhanced corrosion resistance.

*Maintain hardness and strength.

*Almost all alloy steels require heat treatment to achieve their optimum properties.

 

Alloy Steel Schematic diagram of the internal structure of alloy steel

Generation and development of alloy steel

Alloy steel has a history of more than 100 years. More industrial use of alloy steel was about the second half of the 19th century.

In 1868, the British R.F.Mushet invented a self-hardening steel with a composition of 2.5%Mn-7%W, which increased the cutting speed to 5 m/min.

In 1870, a bridge with a span of 158.5 meters was built on the Mississippi River with chromium steel (1.5-2.0%Cr) in the United States; later, some industrial countries switched to nickel steel (3.5%Ni) to build long-span bridges, or used for Build warships.

In 1901, high carbon chromium rolling bearing steel appeared in Western Europe.

In 1910, 18W-4Cr-1V high-speed tool steel was developed, which further increased the cutting speed to 30 m/min.

After the 1920s, stainless steel and heat-resistant steel were introduced during this period.

In 1920, the German E. Maurer invented the 18-8 type stainless acid-resistant steel.

Fe-Cr-Al resistance wire appeared in the United States in 1929.

In 1939, Germany began to use austenitic heat-resistant steel in the power industry.

 

After World War II to the 1960s, it was mainly the era of developing high-strength steel and ultra-high-strength steel. Due to the needs of the aviation industry and the development of rocket technology, many new types of high-strength steel and ultra-high-strength steel appeared, such as Precipitation hardening high-strength stainless steel and various low-alloy high-strength steels are its representative steel grades. After the 1960s, many new metallurgical technologies, especially the out-of-furnace refining technology, were widely used, and alloy steel began to develop in the direction of high purity, high precision and ultra-low carbon, and maraging steel and ultra-pure ferrite appeared. Stainless steel and other new steel grades.

There are thousands of alloy steel grades and tens of thousands of specifications used internationally. The output of alloy steel accounts for about 10% of the total steel output. It is an important metal material widely used in national economic construction and national defense construction.

Since the 1970s, the development of alloyed high-strength steels in the world has entered a new period. Based on the controlled rolling technology and the metallurgy of microalloying, the modern low-alloyed high-strength steels, namely microalloyed steels, have been formed. new concept.

In the 1980s, a variety development involving a wide range of industrial fields and specialized material categories reached its peak with the help of achievements in metallurgical process technology. In the four-in-one relationship of chemical composition-process-structure-property of steel, the dominance of the microstructure and microstructure of steel is highlighted for the first time, and it also shows that the basic research of low-alloy steel has become mature, with unprecedented A new concept for alloy design

The inner world of alloy steel materials

Classification of alloy steel

  1. According to the content of alloying elements

      1) Low alloy steel - the total content of alloying elements is less than or equal to 5%

      2) Medium alloy steel - the total content of alloying elements is between 5% and 10%

      3) High alloy steel - the total content of alloying elements is greater than or equal to 10%

  1. According to the type of alloying elements

      1) Chrome steel

      2) Manganese steel

      3) chrome manganese steel

      4) Chrome Nickel Steel

      5) chrome nickel molybdenum steel

      6) Silicon manganese molybdenum vanadium steel, etc.

  1. According to the main purpose

      1) Structural steel

      2) Tool steel

      3) Special performance steel

There are many types of alloy steel, usually divided into low alloy steel (content <5%), medium alloy steel (content 5% ~ 10%), high alloy steel (content> 10%) according to the content of alloying elements; according to quality, it is divided into high-quality steel Alloy steel, special alloy steel; according to characteristics and uses, it is divided into alloy structural steel, stainless steel, acid-resistant steel, wear-resistant steel, heat-resistant steel, alloy tool steel, rolling bearing steel, alloy spring steel and special performance steel (such as soft magnetic steel). , permanent magnet steel, non-magnetic steel) and so on.

The alloy steel systems of various countries vary according to their respective resource conditions, production and use conditions. Some countries have developed nickel steel and steel systems in the past, while my country has found that silicon, manganese, vanadium, titanium, niobium, boron, lead, Rare earth based alloy steel system. Alloy steel accounts for about ten percent of the total output of steel, and is generally smelted in electric furnaces. Alloy steels can be divided into 8 categories according to their uses. They are: alloy structural steel, spring steel, bearing steel, alloy steel Tool steel, high-speed tool steel, stainless steel, heat-resistant non-skin steel, silicon steel for electrical use.

Our classification of alloy steels:

  1. Quenched and tempered steel

    1) Medium carbon alloy steel with low alloying element content;

    2) High strength;

    3) Used for high temperature bolts, nut materials, etc. [8]

 

  1. Spring steel

    1) The carbon content is higher than that of quenched and tempered steel;

    2) After quenching and tempering treatment, the strength is higher and the fatigue resistance is higher;

    3) For spring material.

 

  1. Rolling bearing steel

    1) High carbon alloy steel with high alloy content;

    2) It has high and uniform hardness and wear resistance;

    3) For rolling bearings.

 

  1. Alloy tool steel - also known as measuring tool steel

    1) High carbon alloy steel with low content of alloying elements;

    2) It has high hardness and wear resistance, good machining performance and good stability;

    3) For measuring tool materials.

 

  1. Special performance steel

    1) Low carbon high alloy steel;

    2) Good corrosion resistance;

    3) For anti-corrosion, some can be used as heat-resistant materials.

 

  1. Heat-resistant steel

    1) Low carbon high alloy steel;

    2) Good heat resistance; 3

For heat-resistant materials, some can be used as anti-corrosion materials.

 

  1. Low temperature steel

    1) Low carbon alloy steel, according to the degree of low temperature resistance, the alloy elements are high or low;

    2) Good low temperature resistance;

    3) For low temperature materials (special steel is nickel steel).

The combination of elements in the alloy

Comparison table of commonly used alloy grades

 

GradeChinaRussiaAmericaBritishJapanFrenchGermany
GBГОСТASTMBSJISNFDIN
High quality carbon structural steel08F08КП1006040A04S09CKC10
881008045M10S9CKC10
10F1010040A10XC10
10101010/1012045M10S10CXC10C10,CK10
15151015095M15S15CXC12C15,CK15
20201020050A20S20CXC18C22,CK22
25251025S25CCK25
30301030060A30S30CXC32
35351035060A35S35CXC38TSC35,CK35
40401040080A40S40CXC38H1
45451045080M46S45CXC45C45,CK45
50501050060A52S50CXC48TSCK53
55551055070M55S55CXC55
60601060080A62S58CXC55C60,CK60
15Mn15Г1016/1115080A17SB46XC1214Mn4
20Mn20Г1021/1022080A20XC18
30Mn30Г1030/1033080A32S30CXC32
40Mn40Г1036/1040080A40S40C40M540Mn4
45Mn45Г1043/1045080A47S45C
50Mn50Г1050/1052030A52S53CXC48
080M50
Alloy Structural Steel20Mn220Г21320/1321150M19SMn42020Mn5
30Mn230Г21330150M28SMn433H32M530Mn5
35Mn235Г21335150M36SMn438(H)35M536Mn5
40Mn240Г21340SMn44340M5
45Mn245Г21345SMn44346Mn7
50Mn250Г2~55M5
20MnV20MnV6
35SiMn35CГEn4637MnSi5
42SiMn35CГEn4646MnSi4
40BTS14B35
45B50B46H
40MnB50B40
45MnB50B44
15Cr15X5115523M15SCr415(H)12C315Cr3
20Cr20X5120527A19SCr420H18C320Cr4
30Cr30X5130530A30SCr43028Cr4
35Cr35X5132530A36SCr430(H)32C434Cr4
40Cr40X5140520M40SCr44042C441Cr4
45Cr45X5145/5147534A99SCr44545C4
38CrSi38XC
12CrMo12XM620Cr.B12CD413CrMo44
15CrMo15XMA-387Cr. B1653STC4212CD416CrMo44
STT42
STB42
20CrMo20XM4119/4118CDS12SCT4218CD420CrMo44
CDS110STT42
STB42
25CrMo4125En20A25CD425CrMo4
30CrMo30XM41301717COS110SCM42030CD4
42CrMo4140708A4242CD442CrMo4
708M40
35CrMo35XM4135708A37SCM335CD434CrMo4
12CrMoV12XMΦ
12Cr1MoV12X1MΦ13CrMoV42
25Cr2Mo1VA25X2M1ΦA
20CrV20XΦ612022CrV4
40CrV40XΦA614042CrV6
50CrVA50XΦA6150735A30SUP1050CV450CrV4
15CrMn15XГ,18XГ
20CrMn20XГCA5152527A60SUP9
30CrMnSiA30XГCA
40CrNi40XH3140H640M40SNC23640NiCr6
20CrNi3A20XH3A331620NC1120NiCr14
30CrNi3A30XH3A3325653M31SNC631H28NiCr10
3330SNC631
20MnMoB80B20
38CrMoAlA38XMIOA905M39SACM64540CAD6.1241CrAlMo07
40CrNiMoA40XHMA4340871M40SNCM43940NiCrMo22
Spring steel60601060080A62S58CXC55C60
8585C1085080A86SUP3
1084
65Mn65Г1566
55Si2Mn55C2Г9255250A53SUP655S655Si7
60Si2MnA60C2ГA9260250A61SUP761S765Si7
9260H
50CrVA50XΦA6150735A50SUP1050CV450CrV4
Rolling bearing steelGCr9ШX9E51100SUJ1100C5105Cr4
51100
GCr9SiMnSUJ3
GCr15ШX15E52100534A99SUJ2100C6100Cr6
52100
GCr15SiMnШX15CГ100CrMn6
Free cutting steelY12A12C1109SUM12
Y15B1113220M07SUM2210S20
Y20A20C1120SUM3220F222S20
Y30A30C1130SUM4235S20
Y40MnA40ГC1144225M3645MF240S20
Wear-resistant steelZGMn13116Г13ЮSCMnH11Z120M12X120Mn12
T7y7W1-7SK7,SK6C70W1
Carbon Tool SteelT8y8SK6,SK5
T8Ay8AW1-0.8C1104Y175C80W1
T8Mny8ГSK5
T10y10W1-1.0CD1SK3
T12y12W1-1.2CD1SK2Y2 120C125W
T12Ay12AW1-1.2CXC 120C125W2
T13y13SK1Y2 140C135W
Alloy Tool Steel8MnSiC75W3
9SiCr9XCBH2190CrSi5
Cr2XL3100Cr6
Cr0613XW5SKS8140Cr3
9Cr29XL100Cr6
WB1F1BF1SK21120W4
Cr12X12D3BD3SKD1Z200C12X210Cr12
Cr12MoVX12MD2BD2SKD11Z200C12X165CrMoV46
9Mn2V9Г2Φ280M8090MnV8
9CrWMn9XBГ1SKS380M8
CrWMnXBГ7SKS31105WC13105WCr6
3Cr2W8V3X2B8ΦH21BH21SKD5X30WC9VX30WCrV93
5CrMnMo5XГMSKT540CrMnMo7
5CrNiMo5XHML6SKT455NCDV755NiCrMoV6
4Cr5MoSiV4X5MΦCH11BH11SKD61Z38CDV5X38CrMoV51
4CrW2Si4XB2CSKS4140WCDS35-1235WCrV7
5CrW2Si5XB2CS1BSi45WCrV7
High speed tool steelW18Cr4VP18T1BT1SKH2Z80WCVS18-0-1
2018/4/1
W6Mo5Cr4V2P6M3N2BM2SKH9Z85WDCVS6-5-2
06-05-04-02
W18Cr4VCo5P18K5Φ2T4BT4SKH3Z80WKCVS18-1-2-5
18-05-04-01
W2Mo9Cr4VCo8M42BM42Z110DKCWVS2-10-1-8
09-08-04-02-01
Stainless Steel1Cr18Ni912X18H9302302S25SUS302Z10CN18.09X12CrNi188
S30200
Y1Cr18Ni9303303S21SUS303Z10CNF18.09X12CrNiS188
S30300
0Cr19Ni908X18H10304304S15SUS304Z6CN18.09X5CrNi189
S30400
00Cr19Ni1103X18H11304L304S12SUS304LZ2CN18.09X2CrNi189
S30403
0Cr18Ni11Ti08X18H10T321321S12SUS321Z6CNT18.10X10CrNiTi189
S32100321S20
0Cr13Al405405S17SUS405Z6CA13X7CrAl13
S40500
1Cr1712X17430430S15SUS430Z8C17X8Cr17
S43000
1Cr1312X13410410S21SUS410Z12C13X10Cr13
S41000
2Cr1320X13420420S37SUS420J1Z20C13X20Cr13
S42000
3Cr1330X13420S45SUS420J2
7Cr17440ASUS440A
S44002
0Cr17Ni7Al09X17H7Ю631SUS631Z8CNA17.7X7CrNiAl177
S17700
Heat resistant steel2Cr23Ni1320X23H12309309S24SUH309Z15CN24.13
S30900
2Cr25Ni2120X25H20C2310310S24SUH310Z12CN25.20CrNi2520
S31000
0Cr25Ni20310SSUS310S
S31008
0Cr17Ni12Mo208X17H13M2T316316S16SUS316Z6CND17.12X5CrNiMo1810
S31600
0Cr18Ni11Nb08X18H12E347347S17SUS347Z6CNNb18.10X10CrNiNb189
S34700
1Cr13MoSUS410J1
1Cr17Ni214X17H2431431S29SUS431Z15CN16-02X22CrNi17
S43100
0Cr17Ni7Al09X17H7Ю631SUS631Z8CNA17.7X7CrNiAl177
S17700
Alloy steel production flow chart